Kinetic study of the methylene blue adsorption on white. Besides, the adsorption kinetics study showed that the adsorption of methylene blue onto the two vacff samples could be best described by the pseudo secondorder model. Adsorption techniques are widely used to remove certain classes of pollutants from waters, especially those which are not easily biodegradable. Adsorption of methylene blue from aqueous solution onto. Data are presented for adsorption of methylene blue from aqueous solutions on two non. Sandwichlike magnesium silicatereduced graphene oxide. Effect of time on the adsorption of methylene blue, methyl.
In this study, natural clay was used as an adsorbent for the removal of methylene blue from an aqueous solution. The results revealed that mb removal mechanisms included. Removal of methylene blue from effluent by using activated. The negative value of free energy change indicated the spontaneous nature of sorption and confirmed affinity of natural jordanian tripoli for the methylene blue. Adsorption of methylene blue on activated charcoal, silica gel and silica article pdf available in asian journal of chemistry 172. Adsorption, methylene blue, kinetic, isotherm, lyonsite structure.
In this work the modified pumice stone has been applied for removal of the methylene blue dye from aqueous. Four isotherm models freundlich, langmuir, redlichpeterson and sips were tested for modeling the adsorption isotherms by. Adsorption of methylene blue from aqueous solutions using. Removal of methylene blue by adsorption onto activated. Adsorption and desorption mechanisms of methylene blue mb removal with ironoxide coated porous ceramics filter iocpcf were investigated in batch and column mode. Adsorption of methylene blue in water onto activated. Adsorption of methylene blue from aqueous solution on activated carbon produced from soybean oil cake by koh activation, biores.
Adsorption of methylene blue on lowcost adsorbents. Adsorption of methylene blue in waste water by low cost. In this paper, the enhanced adsorption of methylene blue mb dye ion on the activated carbon ac modified by three surfactants in. The adsorption equilibrium was represented with langmuir, freundlich and temkin isotherm models. Adsorption of methylene blue in the determination of. Nevertheless, adsorption has proven to be potentially powerful because of its imaginable opportunity to design the chemical composition of the adsorbent surface 35. In this study, jordanian low cost locally available tripoli was studied for its potential use as an adsorbent for removal of a cationic dye methylene blue. Adsorption and desorption mechanisms of methylene blue. Experimental study of methylene blue adsorption from aqueous.
The effect of ph, initial dye concentration, adsorbent dose, the particle size of, agitation speed, temperature, and contact time was explored. Kinetics of methylene blue adsorption on sulphuric acid. Adsorption of methylene blue from industrial effluent. Batch experiments were carried out with treated sawdust and commercial activated carbon to compare the adsorption behavior of them in terms of their adsorption capacities with the initial concentration of 100 mgl and solution ph of 5. Introduction time is crucial to the success of most chemical processes. Adsorption, photocatalytic degradation, surface modification, tio 2 nanoparticles how to cite this article mohammadi a, aliakbarzadeh karimi a. Graphenebased composite is a new type of nanometer materials and with outstanding adsorption capacity of methylene blue than other materials in aqueous solution. Fast adsorption rates are related to high degree of. Removal of methylene blue by adsorption onto activated carbon. In this study, methylene blue was used as the adsorbate to study the removal properties of the porous biochar.
A sandwichlike magnesium silicatereduced graphene oxide nanocomposite mgsirgo with high adsorption efficiency of organic dye and lead ion was synthesized by a hydrothermal approach. Adsorption studies of methylene blue on tio2 nanoparticles. Comparative adsorption isotherms and modeling of methylene. The desired concentrations for adsorption were made by dilution of the stock solution. The obtained adsorption experiment data were then analyzed and interpreted using different models, such as pseudo kinetic models, langmuir and freundlich isotherms and vant. This study investigated the adsorption of methylene blue mb present in wastewater onto the activated carbon produce from lantana camara stem. Pdf adsorption of methylene blue from aqueous solution. In this paper, the enhanced adsorption of methylene blue mb dye ion on the activated carbon ac modified by three surfactants in aqueous solution was researched. The kinetics data related to the adsorption of methylene blue from aqueous solutions are in good agreement with the pseudo.
Pavlova grebenshchikov institute of silicate chemistry, russian academy of sciences, nab. The kinetics of methylene blue mb adsorption onto sacf was described by applying the pseudofirstorder and pseudosecondorder kinetic model with the latter better fitted kinetics data. To test the langmuir and freundlich adsorption models, you will need to calculate x and c for each trial. The effects of ph and temperature of dyesolution on the adsorption capacities have beenevaluated. Adsorption data was better fitted to the langmuir isotherm. The extent of methylene blue removal increased with the increased in contact time, solution ph and amount of adsorbent used.
Adsorption of methylene blue from aqueous solution on. Methylene blue stains to negatively charged cell components like nucleic acids. This paper summarized and compared the difference among graphene, graphenebased composites and other materials in removing methylene blue in aqueous solution. Abstract the adsorption of methylene blue mb on activated carbons prepared from date stones with different degree of activation has been investigated. Noting that 100 ml of a 25 mgl methylene blue mb stock solution was added to each flask, calculate the initial mass of mb before adsorption in mg units. The results in this study indicated that the treated activated carbon was an attractive candidate for removing organic dye of methylene blue which shows great. Adsorption of methylene blue from aqueous solutions by. Pdf adsorption of methylene blue dye using low cost. Adsorption of methylene blue on cellulose from its own. Preparation and characterization of activated carbons from. Various methylene blue solutions with different initial concentrations, in the range of 100 900 mg l. For adsorption processes, the rates of adsorption or the time taken to reach equilibrium is usually monitored. Methylene blue is an organic dyestuff and damaged to human beings. The adsorption of methylene blue was investigated by taking the following values as constant.
Pdf adsorption of methylene blue dye from aqueous solutions by. Adsorption isotherm models, langmuir, freundlich and. Langmuir and tempkin equations were found to have the. Pdf adsorption of methylene blue from aqueous solution onto a. Moreover, the intraparticle diffusion modelling showed that intraparticle diffusion is ratecontrolling for both vacff0 and vacff1600, and external diffusion is also a rate. This paper describes the adsorption of electroactive methylene blue mb dye onto singlewalled carbon nanotubes swnts to form an electrochemically functional nanostructure and its layered nanocomposite. Adsorption of methylene blue from aqueous solutions using natural. Removal of methylene blue from aqueous solution by. Adsorption of methylene blue on the li3fe1xcrxmoo4 3. Effect of methylene blue ph on the adsorption of methylene blue using treated and untreated activated carbons at 50 ppm and 100 ppm. Equilibrium isotherms and kinetic studies of removal of. Mgsi nanopetals were formed in situ on both sides of rgo sheets.
Adsorption studies were performed by batch experiments. Choosing methylene blue as a model dye, adsorption studies of it were carried out on commercially procured p25 tio 2 nanoparticles 21 nm. The equilibrium adsorption data were analyzed using two widely. Anionic surfactantssodium lauryl sulfate sls and sodium dodecyl sulfonate sdsand cationic surfactanthexadecyl trimethyl ammonium bromide ctabwere used for the modification of ac. Data is presented for the adsorption of methylene blue onto activated carbon from aqueous solution. Adsorption, methylene blue, methyl orange, indigocarmine. The influence of various experimental factors such as contact time, initial dye concentration, adsorbent dosage, temperature and ph of dye solution was investigated. For the method of langmuir adsorption capacity k is 0. Sorption of methylene blue dye from aqueous solution using an. Equilibrium behavior of miswak leaves was investigated by performing batch adsorption experiments. The obtained results show that the adsorption of methylene blue onto these mixed oxides is well described by the model of langmuir and its kinetic corresponds to the second order. Equilibrium adsorption data of mb was carried out at 298 k. The nanocomposite with good dispersion of nanopetals exhibits a high specific surface area of 450 m2g and a good mass transportation property.
Adsorption of methylene blue from aqueous solutionsonto unexpanded and expanded perlite samples activatedby h2so4 and nacl solutions has beeninvestigated, to assess the possibility of usingperlite for removing cationic dyes from aqueoussolutions. The chemical structure of methylene blue is given in scheme1. Blue, several studies were devoted to their elimination such as. Adsorption model corresponding to the methylene blue adsorption by activated carbon is the freundlich adsorption model. The results are analyzed within the context of two common adsorption models. The experiments were carried out to explore methylene blue mb uptake by fcbac. Removal of methylene blue from wastewater by adsorption. Methylene blue mb is frequently utilized as a model cationic dye in adsorption studies 16,17,18. The adsorption equilibrium of methylene blue was best describe by. The main objective of the study was to remove methylene blue by using low cost adsorbent like rice husk and it was found this material can used as adsorbent for removal of methylene blue dye. Pdf adsorption of methylene blue onto treated activated. Adsorption kinetics of methylene blue from aqueous.
Adsorption of methylene blue from aqueous solutions by synthetic montmorillonites of different compositions o. Abstract the adsorption kinetics of methylene blue from aqueous solutions on purified palygorskite was investigated. The amount of methylene blue adsorbed onto rectorite was calculated by using the following expression. The experimental data for adsorption of methylene blue on activated carbon have been fitted to both. Water free fulltext adsorption of methylene blue in. The kinetics and mechanism of methylene blue mb adsorption onto activated carbon fibers acfs have been studied. Removal of methylene blue from aqueous solution using.
The effects of mb 0, ph, contact time and adsorbent dose were evaluated. In this study, coconut frond treated with sulphuric acid sacf was used as a lowcost adsorbent in removing methylene blue mb from aqueous solutions. Adsorption of methylene blue from aqueous solution onto viscosebased activated carbon fiber felts. Methylene blue adsorption onto modified lignin from sugar. Adsorption studies were performed by the batch technique to obtain rate and equilibrium data. The adsorption isotherms were found to better fit the langmuir than the freundlich model, and the adsorption kinetics fitted a pseudosecondorder model. Chemical structure of methylene blue the adsorption experiments were carried out in 250 ml erlenmeyer flasks. The removal of methylene blue by activated carbon of corn husk by zncl 2 activation was investigated in the present study.
Adsorption of methylene blue onto activated carbon. C 0 and ce are the initial methylene blue concentration mg l1 and methylene blue concentration. In this work is presented the use of reticu lated formic lignin as an adsorbent material for methylene blue removal. Rapid adsorption of methylene blue from aqueous solutions. The feasibility of sawdust as low cost adsorbent to remove methylene blue from aqueous solutions was investigated through batch and column studies. Ftir analysis showed that carbonyl and hydroxyl groups. A pseudofirst order reaction equation is found to be matches well with the experimental data suggesting that adsorption of methylene blue on tio 2 nanoparticles is a surface controlled reaction step. Adsorption kinetics studies indicated that the pseudosecondorder model yielded the best fit for the kinetic data. Adsorption of methylene blue dye onto carbon nanotubes. Potential adsorption of methylene blue from aqueous.1544 596 1095 655 767 1203 1594 697 255 1595 554 1332 1521 773 1513 733 436 1275 751 1589 1249 845 446 806 1224 212 1185 496 1089 1318 1028 565 1211